Mondays, Wednesdays, and Fridays 230-320 PM, in 358 Willard.
Prerequisites: Chemistry 451 and 452 or equivalents.
Class url: http://stm1.chem.psu.edu/~psw/Chem597f02.html (check for frequent updates)
Jump to: Next class | Learning | Some www sites | Texts | Grading | Current version date
Current Science Seminars
Faculty
Professor Mary Beth Williams
Office: 204 Chandlee
Phone: (814) 865-8859
E-mail: mbw@chem.psu.edu
Instant Messenger: nbkybtst32
Office Hours: By appointment or AIM
Send e-mail to Prof. Williams
Secretary: Amy Luzier, 224 Chandlee, (814) 865-4041
Professor Paul S. Weiss
Office: 407 Davey Laboratory
Phone: (814) 865-3693
E-mail: stm@psu.edu
Instant Messenger: PSWeiss
Office Hours: By appointment or AIM
Send e-mail to Prof. Weiss
Staff assistant: Stephen Bumbarger, 415 Davey Laboratory, (814) 865-7817, sxb10@psu.edu, Catsman4 (AIM)
We also have excellent guest lecturers planned.
Learning in Chem 597A
There is a tremendous amount to learn in this new field and in this new course. Several scientific communities are part of nanoscience and speak largely in different languages. These fields include chemistry, physics, biology, computer science, neuroscience, electrical engineering, chemical engineering, mechanical engineering, and bioengineering. Our goal is to give you enough background (and language training) to understand current research in these areas through talks and papers. This will require a great deal of work on your part.
Anticipate that the lectures, the readings, and the homeworks will be complementary rather than overlapping. You will be responsible for the material from all of these sources. Similarly, your participation in class is required both for discussions and for the education of your classmates and professors. There is nothing that we plan to say that is so critical that a good classroom discussion would not be preferable.
This is a very dynamic subject with rapidly changing perspectives and many advances. You will learn about these by pointers to the current literature and by taking advantage of the many seminars in this field available at Penn State throughout the semester and beyond. You should plan to stay current in the literature as there are weekly, if not daily, advances. (There are a number of ways to access current advances.)
Text
We have not found an adequate text for this course yet. Instead, we will use selected papers and work from the current (and future) literature.
Selected groups at Penn State
Research in Prof. Williams' group.
Research in Prof. Weiss' group.
Research in Prof. Allara's group.
Research in Prof. Castleman's group.
Research in Prof. Crespi's group.
Research in Prof. Eklund's group.
Penn State Nanofab.
Research in Prof. Jackson's group.
Research in Prof. Keating's group.
Research in Prof. Mallouk's group.
Research in Prof. Mayer's group.
Selected groups elsewhere
MITRE Nanosystems Group.
Research in Chad Mirkin's group at Northwestern University.
US National Nanotechnology Initiative.
Research in Prof. James Tour's Group at Rice University.
Current Science Seminars
Class Topics and Readings
These topics and assignments are subject to change, and you should check back regularly (be sure to hit Reload on your browser). We will try to indicate changes for you.
During the semester we will cover:
Electronic, optical, and magnetic properties of nanostructures -- Molecules to quantum dots to coupled nanostructures
Self- and directed assembly
Bottom up vs. top down
Molecular electronics
Molecular motors
Nanotubes, nanowires, and nanodevices
Nanoscale analyses: scanning probes, electron microscopies, spectroscopies, electrochemical methods
Connecting to the outside world
Wednesday 28 August 2002 Class (Weiss & Williams)
Class Introduction
Introduction to nanoscience: Fundamental concepts
Friday 30 August 2002 (Weiss)
Introduction to nanoscience: Solid and surface spectroscopy
Monday 2 September 2002
Labor Day - no class.
Wednesday 4 September 2002 Class (Weiss)
Nanolithography I: Electrons, Ions, & Photons
References
Alkaisi, Maan M.; Blaikie, Richard J.; McNab, Sharee J. Nanolithography in the evanescent near-field. Advanced Materials (2001), 13(12-13), 877-887.
http://www3.interscience.wiley.com/cgi-bin/abstract/84503261/START
Friday 6 September 2002 Class
In lieu of class, please attend Dr. Debra Rolison's lecture in 117 HUB at 230 PM.
Monday 9 September 2002 Class (Weiss)
Self-assembly I: Monolayers
& Student presentations
References
Ulman, Abraham. Formation and Structure of Self-Assembled Monolayers. Chemical Reviews (1996), 96(4), 1533-1554.
http://pubs.acs.org/journals/chreay/article.cgi/chreay/1996/96/i04/pdf/cr9502357.pdf
Homework #1 Due: 2-3 page report on a paper on nanoscience published in 2001 or 2002 (or to be published in 2003). The paper can be found in Science, Nature, Physical Review Letters, Journal of the American Chemical Society, or Nano Letters. Another journal can only be used if your article is specifically approved by one of the instructors. Keep in mind the science/instrumental/clutter issue discussed in class.
Describe the techniques used and experimental conditions.
See a more complete description of the paper requirements.
Prepare a single transparency on the subject covered to introduce it to the class. Four students will be called upon to present this and each subsequent assignment. Bring this viewgraph to the two subsequent classes, as well.
Wednesday 11 September 2002 Class (Weiss)
Self-assembly II: Monolayers, cont.
& Student presentations
References
Niemeyer, Christof M. Self-assembled nanostructures based on DNA: towards the development of nanobiotechnology. Current Opinion in Chemical Biology (2000), 4(6), 609-618.
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6VRX-41S4Y7C-5-9&_cdi=6246&_orig=search&_coverDate=12%2F01%2F2000&_qd=1&_sk=999959993&wchp=dGLbVtb-lSzBS&_acct=C000014439&_version=1&_userid=209810&md5=94db7dbe581e7430098aa3801de193c2&ie=f.
Mbindyo, Jeremiah K. N.; Reiss, Brian D.; Martin, Benjamin R.; Keating, Christine D.; Natan, Michael J.; Mallouk, Thomas E. DNA-directed assembly of gold nanowires on complementary surfaces. Advanced Materials (2001), 13(4), 249-254.
http://www3.interscience.wiley.com/cgi-bin/fulltext?ID=77004433&PLACEBO=IE.pdf
Mirkin, Chad A. Programming the Assembly of Two- and Three-Dimensional Architectures with DNA and Nanoscale Inorganic Building Blocks. Inorganic Chemistry (2000), 39(11), 2258-2272.
http://pubs.acs.org/journals/inocaj/article.cgi/inocaj/2000/39/i11/pdf/ic991123r.pdf
Fendler, Janos H. Self-Assembled Nanostructured Materials. Chemistry of Materials (1996), 8(8), 1616-1624.
http://pubs.acs.org/journals/cmatex/article.cgi/cmatex/1996/8/i08/pdf/cm960116n.pdf
Hostetler, Michael J.; Murray, Royce W. Colloids and self-assembled monolayers. Current Opinion in Colloid & Interface Science (1997), 2, 42-50.
Jun-Fu Liu, Sylvain Cruchon-Dupeyrat, Jayne C. Garno, Gang-Yu Liu, Three-Dimensional Nanostructure Construction via Nanografting: Positive and Negative Pattern Transfer, NanoLetters, ASAP
http://dx.doi.org/10.1021/nl025670c
Friday 13 September 2002 Class (Weiss)
Nanolithography II: Soft lithography
References
Xia, Younan; Whitesides, George M. Soft lithography. Polymeric Materials Science and Engineering (1997), 77 596-598.
Whitesides, George M.; Ostuni, Emanuele; Takayama, Shuichi; Jiang, Xingyu; Ingber, Donald E. Soft lithography in biology and biochemistry. Annual Review of Biomedical Engineering (2001), 3 335-373.
NEW:
Microcontact Printing
Patterning Self -Assembled Monolayers: Applications in Materials Science
Kumar, A.; Biebuyck, H. A; Whitesides, G. M. Langmuir 10, 1498-1511 (1994).
Microcontact printing of self-assembled monolayers: applications in microfabrication
Wilbur, J. L.; Kumar, A.; Biebuyck, H. A.; Kim, E.; Whitesides, G. M.
Nanotechnology 7, 452-457 (1996).
MIMIC
Micromolding in Capillaries: Applications in Materials Science
Kim, E.; Xia, Y. N.; Whitesides, G. M. Journal of the American Chemical Society 118, 5722-5731
(1996).
Micromolding of Polymers in Capillaries: Applications in Microfabrication
Xia, Y. N.; Kim, E.; Whitesides, G. M. Chem. Materials 8, 1558-1567 (1996).
Monday 16 September 2002 Class (Williams)
Self-assembly III: 3-D Assembly
Covalent and electrostatic assembly, DNA-based assembly
Reduced Transition Metal Colloids: A Novel Family of Reusable Catalysts?
in press, A. Roucoux, J. Schulz, and H. Patin*
http://pubs.acs.org/journals/chreay/asap.cgi/chreay/asap/pdf/cr010350j.pdf
Wednesday 18 September 2002 Class (Williams)
Characterization I: Spectroscopy
Friday 20 September 2002 Class (Guest Lecturer: Dr. Thomas P. Pearl)
Characterization II: Spectroscopy
Homework #2 Due: 2-3 page report on a paper on self-assembly, in some form. The paper can be found in Science, Nature, Physical Review Letters, Journal of the American Chemical Society, or Nano Letters. Another journal can only be used if your article is specifically approved by one of the instructors. Keep in mind the science/instrumental/clutter issue discussed in class.
Describe the techniques used and experimental conditions.
See a more complete description of the paper requirements.
Monday 23 September 2002 Class (Weiss)
Characterization III: Scanning Probe Microscopies I
& Student presentations
References
McCarty, G. S.; Weiss, P. S. Scanning Probe Studies of Single Nanostructures. Chemical Reviews (1999), 99, 1983-1990.
http://pubs.acs.org/journals/chreay/article.cgi/chreay/1999/99/i07/pdf/cr970110x.pdf
Gimzewski, James K.; Joachim, Christian. Nanoscale science of single molecules using local probes. Science (1999), 283, 1683-1688.
Shiku, Hitoshi; Dunn, Robert C. Near-field scanning optical microscopy. Analytical Chemistry (1999), 71, 23A-29A.
Poggi, Mark A.; Bottomley, Lawrence A.; Lillehei, Peter T. Scanning Probe Microscopy. Analytical Chemistry (2002), 74(12), 2851-2862.
http://pubs.acs.org/journals/ancham/article.cgi/ancham/2002/74/i12/pdf/ac025695w.pdf
Lillehei, Peter T.; Bottomley, Lawrence A. Scanning Probe Microscopy. Analytical Chemistry (2000), 72(12), 189-196.
http://pubs.acs.org/journals/ancham/article.cgi/ancham/2000/72/i12/pdf/a10000108.pdf
Monday 23 September 2002, 7 PM, S5 Osmond
Please try to attend Paul Weiss's lecture:
Exploring and Controlling the Atomic-Scale World
of the research seminar series for entering chemistry graduate students, pizza + provided.
Wednesday 25 September 2002 (Weiss)
Characterization IV: Scanning Probe Microscopies II
References
Liu, Gang-Yu; Xu, Song; Qian, Yile. Nanofabrication of Self-Assembled Monolayers Using Scanning Probe Lithography. Accounts of Chemical Research (2000), 33(7), 457-466.
http://pubs.acs.org/journals/achre4/article.cgi/achre4/2000/33/i07/pdf/ar980081s.pdf
Demers, L. M.; Ginger, D. S.; Park, S.-J.; Li, Z.; Chung, S.-W.; Mirkin, C. A. Direct patterning of modified oligonucleotides on metals and insulators by dip-pen nanolithography. Science (2002), 296(5574), 1836-1838.
Schwartz, Peter V. Molecular transport from an atomic force microscope tip: A comparative study of dip-pen nanolithography. Langmuir (2002), 18(10), 4041-4046. (CONTROVERSY PAPER)
http://pubs.acs.org/journals/langd5/article.cgi/langd5/2002/18/i10/pdf/la011652j.pdf
Friday 27 September 2002 (Weiss & Williams)
Characterization V: Electron and Optical Microscopies
& Student presentations
See the article on Hendrik Schön in the NY Times.
Links to the summary and full reports from Lucent on the issue.
Monday 30 September 2002 Class (Weiss)
Scanning Probes, cont.
Wednesday 2 October 2002 Class (Weiss)
Nanomaterials & Nanostructures I: Fullerenes, Nanotubes, Metcars I
Friday 4 October 2002 Class (Williams)
Nanomaterials & Nanostructures II: Metal Nanoparticles I
& Student presentations
Homework #3 Due: 2-3 page report on a paper using at least three of the characterization tools we discussed to learn something other than structure(s). The paper can be found in Science, Nature, Physical Review Letters, Journal of the American Chemical Society, or Nano Letters. Another journal can only be used if your article is specifically approved by one of the instructors. Keep in mind the science/instrumental/clutter issue discussed in class.
Describe the techniques used and experimental conditions.
See a more complete description of the paper requirements.
Friday 4 October 2002, 7 PM, S5 Osmond
Please try to attend Mary Beth Williams's lecture:
Directing Electron and Mass Transport in Nanostructured Materials
of the research seminar series for entering chemistry graduate students, pizza + provided.
Monday 7 October 2002 Class (Williams)
Nanomaterials & Nanostructures IV: Metal Nanoparticles II
& Student presentations
Assignment: What are C-C bond lengths and strengths for single, double, and triple bonds? (e.g. in ethane, ethylene, and acetylene, respectively)
Wednesday 9 October 2002 Class (Weiss & Williams)
Exam I Review
Covering all lectures, readings, and presentations through Metal Nanoparticles
Friday 11 October 2002 Class
Exam I
Monday 14 October 2002 Class
No class -- Fall Break
Wednesday 16 October 2002 Class (Weiss & Williams)
Go over exam
Nanomaterials & Nanostructures V:
Quantum Dots (Semiconductor Nanoparticles) I
References
Manna, Liberato; Scher, Erik C.; Li, Liang-Shi; Alivisatos, A. Paul. Epitaxial Growth and Photochemical Annealing of Graded CdS/ZnS Shells on Colloidal CdSe Nanorods. Journal of the American Chemical Society (2002), 124(24), 7136-7145.
http://pubs.acs.org/journals/jacsat/article.cgi/jacsat/2002/124/i24/pdf/ja025946i.pdf
Quantum Dot Review: http://pubs.acs.org/subscribe/journals/ancham-a/74/i19/pdf/1002murphy.pdf
Friday 18 October 2002 (Weiss & Williams)
Optical Properties of Metallic Nanoparticles
& Student presentations
Homework #4 Due: 2-3 page report on a paper on nanoparticles. The paper can be found in Science, Nature, Physical Review Letters, Journal of the American Chemical Society, or Nano Letters. Another journal can only be used if your article is specifically approved by one of the instructors. Keep in mind the science/instrumental/clutter issue discussed in class.
Describe the techniques used and experimental conditions.
See a more complete description of the paper requirements.
Monday 21 October 2002 Class (Williams)
Nanomaterials & Nanostructures VI:
Quantum Dots (Semiconductor Nanoparticles) II
& Student presentations
Wednesday 23 October 2002 Class(Williams & Weiss)
Nanomaterials & Nanostructures VII: Quantum Dots (Semiconductor Nanoparticles) III
Student presentations
& In class exercise
Friday 25 October 2002 Class (Vin Crespi, PSU Physics)
Fullerenes
Monday 28 October 2002 Class (Williams)
Microelectronics & Nanoelectronics II: Single Electron Devices
(including a cautionary tale)
& Presentations from in class exercise
Wednesday 30 October 2002 Class (Weiss)
Microelectronics & Nanoelectronics III: Molecular Electronics I
References
Colbert, Daniel T.; Smalley, Richard E.. Fullerene nanotubes for molecular electronics. Trends in Biotechnology (1999), 17(2), 46-50.
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TCW-3WRB2VP-3-5&_cdi=5181&_orig=search&_coverDate=02%2F01%2F1999&_qd=1&_sk=999829997&wchp=dGLbVlz-lSzBA&_acct=C000014439&_version=1&_userid=209810&md5=e05d1e989cf6c5f73c975ea17426d09d&ie=f.
Friday 1 November 2002 Class (Weiss)
Microelectronics & Nanoelectronics IV: Molecular Electronics II
& Student presentations
Homework #5 Due: 2-3 page report on a paper on nanoelectronics. The paper can be found in Science, Nature, Physical Review Letters, Journal of the American Chemical Society, or Nano Letters. Another journal can only be used if your article is specifically approved by one of the instructors. Keep in mind the science/instrumental/clutter issue discussed in class.
Describe the techniques used and experimental conditions.
See a more complete description of the paper requirements.
Monday 4 November 2002 Class (Weiss)
Microelectronics & Nanoelectronics V: Molecular Electronics III
& Student presentations
Wednesday 6 November 2002 Class (Williams)
Exam II review
Friday 8 November 2002 Class (Williams)
Exam II --
NOTE CHANGED DATE
covering through microelectronics and nanoelectronics
Monday 11 November 2002 Class (Weiss)
Go over Exam II
Nanoscale Optoelectronics I
Wednesday 13 November 2002 Class (Weiss)
Nanoscale Optoelectronics II
Friday 15 November 2002 (Weiss & Williams)
Go Over All Paper Topics (all students present)
Nanoscale Optoelectronics III
Homework #6 Due: 2-3 page paper focusing on a recent article that is a key reference for your final paper.
See a more complete description of the paper requirements.
Monday 18 November 2002 Class (Williams)
Magnetic Systems
Wednesday 20 November 2002 (Weiss)
Nanobiotechnology I: Biomimetics & control
Friday 22 November 2002 (Williams)
Nanobiotechnology II: Biosensors
References
Maxwell, Dustin J.; Taylor, Jason R.; Nie, Shuming. Self-Assembled Nanoparticle Probes for Recognition and Detection of Biomolecules. Journal of the American Chemical Society (2002), 124(32), 9606-9612.
http://pubs.acs.org/journals/jacsat/article.cgi/jacsat/2002/124/i32/pdf/ja025814p.pdf
DNA with dip pen nanolithography (Chad Mirkin)
Feldheim's linked dimeric/trimeric/tetrameric nanoparticles
Pete Schwartz's dip pen nanolithography and a follow-up paper Molecular Transport from an Atomic Force Microscope
Tip: A Comparative Study of Dip-Pen Nanolithography
Colorometric DNA detector (Chad Mirkin)
Monday 25 November 2002 Class (Weiss & Williams)
Nanobiotechnology III: Biosensors, cont.
Wednesday 27 November 2002
No class - Thanksgiving
Friday 29 November 2002
No class - Thanksgiving
Monday 2 December 2002 Class (Williams)
Go over paper topics.
Nanobiotechnology IV: Biomolecular motors
Wednesday 4 December 2002 Class (Williams)
Nanobiotechnology V: Nanofluidics & Lab on a Chip I
Friday 6 December 2002 Class (Weiss)
Go over paper topics.
Final paper due.
See a more complete description of the final paper requirements.
Monday 9 December 2002 Class (Weiss & Williams)
Final Review
Wednesday 11 December 2002 Class (Weiss & Williams) CLASS CANCELLED FOR ICE!
7 30 PM - ??? FINAL EXAM. EXAM CANCELLED FOR ICE!
Closed book, nearly unlimited time.
Friday 13 December 2002 Class (Weiss & Williams)
RESCHEDULED FINAL EXAM IN CLASS
Stay late to complete the exam. If you cannot stay past 330 PM, please contact Mary Beth and Paul.
Grading
1. Class participation: 10%
2. Short (2-3 pages max.) reviews of published research papers on current
lecture topics: 25%
6 will be required during the semester
A photocopy or print of source article must be attached
Short (<5) minute oral presentations of interesting papers are encouraged. One or two can be accommodated each class.
See a more complete description of the paper requirements
3. Two midterm exams: 15% each
3. One final exam: 25%
4. One long paper reviewing the literature on an approved topic: 20%
topic must involve course material
10 pages typical with 10-20+ references
graded on difficulty of material, clarity, organization, critical/innovative input of student, + related criteria
Consider the following examples of areas from which paper topic can be drawn:
Nanoparticle properties
Nanoparticle-based sensors
Molecular electronics
Hybrid biolgical/synthetic motors
See a more complete description of the paper requirements
TOTAL: 110%, because that is what we expect from you!
All Penn State policies (http://www.psu.edu/ufs/policies/) regarding ethics
and honorable behavior apply to this course.
Papers
Choose a topic from the current, primary literature that is related to the nanoscience topic listed below. The paper must have been published no earlier than January 1, 2001, and should be taken from the journals Science, Nature, Journal of the American Chemical Society, Nanoletters, Applied Physics Letters, or Physical Review Letters. Papers from other journals are permitted only with prior consent.
Spend time selecting your paper. You are going to put a lot of effort into working on it, so it should be something of interest to you and others, and it should be important
Know the leader(s) and location(s) of the group(s) performing the work. Look up the papers cited in order to understand the background and context of the paper.
Use spell checking and proof read your paper: your paper will be returned, ungraded, if there are large numbers of typographical, spelling and/or grammatical errors.
Short Papers focus on a single published paper and are not to exceed 3 typed pages, including references and figures. In addition to the paper covered, you are expected to reference related, cited and subsequent work. The sixth short paper may be on any nanoscience topic, and will form the basis of the full paper.
The Full Paper focuses on a single topic, includes multiple papers and/or the work of multiple research groups, is typically 10 typed pages and is not to exceed 12 typed pages including references and figures. This paper is an expanded version of one of the short papers. The full paper should include abstract, introduction, experimental results and discussion, and conclusion sections.
Use the following formatting defaults:
• All margins are a minimum of 1”.
• Font no less than 12 point.
• Line spacing no less than 1.5 lines.
• Include page numbers.
Title Page (which is not included in the page limit): Include your name, date, email address, and full reference for the paper you are discussing.
Figures: Use illustrative examples only (do not attempt to fill space by incorporating copious numbers of figures). Include a figure legend.
References: Use one of the following formats:
Tang, Z.; Kotov, N. A.; Giersig, M. “Spontaneous Organization of Single CdTe Nanoparticles into Luminescent Nanowires” Science 2002, 297 (5579), 237 – 240.
or
“Spontaneous Organization of Single CdTe Nanoparticles into Luminescent Nanowires,” Z. Tang, N. A. Kotov, and M. Giersig, Science 297, 237 – 240 (2002).
Papers are due by class time on the dates indicated, and neither late papers nor electronic submissions will be accepted. For each short paper, come to class with a single viewgraph overview that you can use to explain the key elements of the paper. You may include both figures and text on the viewgraph, and these should be readable from the back of the room (this may mean retyping or redrawing).
You should be prepared to talk for approximately 5 minutes and to justify your choice of paper.
Version date: 11 December 2002 (back to the top)
mbw & psw